Bruce Foxman
Degrees
Massachusetts Institute of Technology, Ph.D.Iowa State University, B.S.
Expertise
X-ray structure determination. Coordination polymers. Chemical, physical, and crystallographic studies of solid-state reactions. Automatic solution of crystal structures using novel computer techniques. Development of nwe crystallographic software to analyze twinning in crystals.Profile
Solid-State Reactions, Phase Transitions and Polymorphism WebpageAwards and Honors
Fellow of the American Crystallographic Association (2020)
Fellow of the Royal Society of Chemistry (2017)
70th Birthday Symposium (published) in Honor of Bruce M. Foxman by the American Crystallographic Association (2012 - 2013)
Brandeis Prize for Excellence in Teaching (2009)
Professeur Invite, Universite Louis Pasteur, Strasbourg (2002)
Honorary Professor, University of Brirmingham (UK) (2001)
Visiting Professor, Max-Planck-Institut fuer Polymerforschung (1995 - 1996)
Chair, College Board AP Chemistry Committee (1993 - 1996)
Visiting Professor, Oxford University (1987)
Visiting Professor, IBM Thomas J. Watson Research Center (1975)
Research Fellow, The Australian National University (1968 - 1972)
National Institutes of Health Predoctoral Fellow (1965 - 1966)
National Science Foundation Summer Teaching Fellow (1965)
National Science Foundation Undergraduate Research Participant (1962 - 1964)
Scholarship
Skell, J. M.; Kahn, M.; Foxman, B. M.. "Δ9-Tetrahydrocannabinolic acid A, the precursor to Δ9-tetrahydrocannabinol (THC)." Acta Crystallogr. Sect. C: Struct. Chem. (2021): accepted for publication. (forthcoming)
A Series of Dimeric Cobalt Complexes Bridged by N-Heterocyclic Phosphido Ligands. "Poitras, A. M.; Bezpalko, M. W.; Moore, C. E.; Dickie, D. A.; Foxman, C. M.; Thomas, C. M.." Inorg. Chem. 59. (2020): 4729-4740; DOI: 10.1021/acs.inorgchem.9b03790.
Beattie, J. W.; Wang, C.; Zhang, H.; Krogman, J. P.; Foxman, B. M.; Thomas, C. M.. "Dimerization of terminal alkynes promoted by a heterobimetallic Zr/Co complex." Dalton Trans. 49. (2020): 2407-2411; DOI: 10.1039/D0DT00334D.
Heyman, J. B.; Chen, C.-H.; Foxman, B. M.. "On the Crystal Structures of Missing Links in the Early History of Solid-State Reactions: The Group IA Acrylates and Methacrylates." Cryst. Growth Des. 20. (2020): 330-336; DOI: 10.1021/acs.cgd.9b01267.
Shang, W.; Schlam, R. F.; Hickey, M. B.; Zhou, J.; Wheeler, K. A.; Diaz de Delgado, G. C.; Chen, C.-H.; Snider, B. B.; Foxman, B. M.. "Chemo- and Stereospecific Solid-State Thermal Dimerization of Sodium trans-2-Butenoate and γ-Ray-Induced Single-Crystal-to-Single-Crystal Dimerization of Hexaaquamagnesium trans-2-Butenoate Dihydrate: Both Give rel-(3S,4R)-1-Hexene-3,4-dicarboxylate but." Cryst. Growth Des. 21. (2020): 663–682; DOI: 10.1021/acs.cgd.0c01466.
Trotta, J. T.; Zeidan, T. A.; Tilak, P. A.; Foxman, B. M.; Almarsson, Ö.; Oliveira, M. A.; Chiarella, R. A.; Hickey, M. B.; Remenar, J. F.. "Aripiprazole and Dehydro-Aripiprazole Solid Solutions: Crystalline Combinations of Drug and Active Metabolite in Tailored Compositions." Cryst, Growth Des. 20. (2020): 3944-3956; DOI: 10.1021/acs.cgd.0c00263.
Barden, B. A.; Culcu, G.; Krogman, J. P.; Bezpalko, M. W.; Hatzis, G. P.; Dickie, D. A.; Foxman, B. M.; Thomas, C. M.. "Assessing the Metal–Metal Interactions in a Series of Heterobimetallic Nb/M Complexes (M = Fe, Co, Ni, Cu) and Their Effect on Multielectron Redox Properties." Inorg. Chem. 58. (2019): 821–833; DOI: 10.1021/acs.inorgchem.8b02960.
Cooperative activation of O–H and S–H bonds across the Co–P bond of an N-heterocyclic phosphido complex. "Poitras, A. M.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.." Dalton Trans. 48. (2019): 3074-3079; DOI:10.1039/C8DT05052J.
Gramigna, K. M.; Dickie, D. A.; Foxman, B. M.; Thomas, C. M. "Cooperative H2 Activation across a Metal–Metal Multiple Bond and Hydrogenation Reactions Catalyzed by a Zr/Co Heterobimetallic Complex." ACS Catalysis 9. (2019): 3153-3164 DOI: 10.1021/acscatal.8b.
Zhang, H.; Moore, C. E.; Dickie, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "O2 Activation by a Heterobimetallic Zr/Co Complex." J. Am. Chem. Soc. 141. (2019): 9516-9520; DOI: 10.1021/jacs.9b04215..
; Hu, B.; Bezpalko, M. W.; Fei, C.; Dickie, D. A.; Foxman, B. M.; Deng, L.. "Origin of and a Solution for Uneven Efficiency by Cinchona Alkaloid-Derived, Pseudoenantiomeric Catalysts for Asymmetric Reactions." J. Am. Chem. Soc. 140. (2018): 13913–13920; DOI: 10.1021/jacs.8b09010..
Fitch, R. W.; Snider,B. B.; Zhou, Q.; Foxman, B. M.; Pandya, A. A.; Yakel, J. L.; Olson, T. T.; Al-Muhtasib, N.; Xiao, Y.; Welch, K. D.; Panter, K. E.. "Absolute Configuration and Pharmacology of the Poison Frog Alkaloid Phantasmidine." J. Nat. Prod. 2018 81. (2018): 1029–1035, DOI: 10.1021/acs.jnatprod.8b0006.
Lorson, L. C.; Tai, O.; Foxman, Bruce M.. "Use of Topotactic Phase Transformations to Obtain Solutions of the Crystal Structures of Highly Disordered Materials." Cryst. Growth Des. 18. (2018): 409-415; DOI: 10.1021/acs.cgd.7b01406.
Poitras, A. M.; Knight, S. E.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Addition of H2 Across a Cobalt-Phosphorus Bond." Angew. Chem. Int. Ed. 57. (2018): 1497-1500; DOI: 10.1002/anie.201710100.
Reiner, B.; Mucha, N.; Rothstein, A.; Temme, S.; Duan, P.; Schmidt-Rohr, K.; Foxman, B. M.; Wade, C.;. "Zirconium Metal-Organic Frameworks Assembled from PNNNP Pd and Pt Pincer Complexes: Synthesis, Postsynthetic Modification, and Lewis Acid Catalysis." Inorg. Chem. 57. (2018): 2663–2672; ASAP; DOI: 10.1021/acs.inorgchem.7b03063.
Steinberg, B. D.; Harris , E. T.; Foxman, B. M.; Oliveira, M. A.; Hickey, M. B.. "A New Look at Naltrexone Hydrochloride Hydrates: Understanding Phase Behavior and Characterization of Two Dihydrate Polymorphs." Cryst. Growth. Des. 18. (2018): 3502–3509 ; DOI: 10.1021/acs.cgd.8b00262.
Bezpalko, M. W.; Poitras, A. M.; Foxman, B. M.; Thomas, C. M.. "Cobalt N-Heterocyclic Phosphenium Complexes Stabilized by a Chelating Framework: Synthesis and Redox Properties." Inorg. Chem. 56. (2017): 503–510; DOI: 10.1021/acs.inorgchem.6b02374.
Culcu, G.; Iovan, D. A.; Krogman, J. P.; Wilding, M. J. T.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Heterobimetallic Complexes Comprised of Nb and Fe: Isolation of a Coordinatively Unsaturated NbIII/Fe0 Bimetallic Complex Featuring a Nb≡Fe Triple Bond." J. Am. Chem. Soc. 139. (2017): 9627–9636; DOI: 10.1021/jacs.7b04151.
Evers-McGregor; D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Exploring the coordination chemistry of N-heterocyclic phosphenium/phosphido ligands using nickelocene as a synthon." Inorg. Chim. Acta 460. (2017): 17-21; http://dx.doi.org/10.1016/j.ica.2016.10.001.
Reiner, B. R.; Foxman, B. M.; Wade, C. R.. "Electrochemical and structural investigation of the interactions between naphthalene diimides and metal cations." Dalton Trans. 46. (2017): 9472-9480; http://dx.doi.org/10.1039/C7DT02067H.
Zhang, H.; Wu, B.; Marquard, S. L.; Litle, E. D.; Dickie, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Investigation of Ketone C═O Bond Activation Processes by Heterobimetallic Zr/Co and Ti/Co Tris(phosphinoamide) Complexes." Organometallics 36. (2017): 3498-3507; DOI: 10.1021/acs.organomet.7b00445.
Evers-McGregor, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "N-heterocyclic phosphenium and phosphido nickel complexes supported by a pincer ligand framework." Dalton Trans. 45. (2016): 1918-1929; DOI: 10.1039/C5DT03549J.
Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Multi-electron redox processes at a Zr(IV) center facilitated by an appended redox-active cobalt-containing metalloligand." Dalton Trans. 45. (2016): 11182-11190; DOI: 10.1039/C6DT01498D.
Reiner, B. R.; Bezpalko, M. W.; Foxman, B. M.; Wade, C. R.. "Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes." Organometallics 35. (2016): 2830-2835; DOI: 10.1021/acs.organomet.6b00403.
Saper, N. I.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Synthesis of chiral heterobimetallic tris(phosphinoamide) Zr/Co complexes." Polyhedron 114. (2016): 88-95.
Wu, B; Wilding, M. J. T.; Kuppuswamy, S.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Exploring Trends in Metal–Metal Bonding, Spectroscopic Properties, and Conformational Flexibility in a Series of Heterobimetallic Ti/M and V/M Complexes (M = Fe, Co, Ni, and Cu)." Inorg. Chem. 55. (2016): 12137–12148; DOI: 10.1021/acs.inorgchem.6b01543.
Zeidan, T. A. ; Trotta, J. T.; Tilak, P. A.; Oliveira, M. A.; Chiarella, R. A.; Foxman, B. M.; Almarsson, Ö.; Hickey, M. B.. "An unprecedented case of dodecamorphism: the twelfth polymorph of aripiprazole formed by seeding with its active metabolite." CrystEngComm 18. (2016): 1486-1488 ; DOI: 10.1039/C5CE02467F.
Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Use of a Bidentate Ligand Featuring an N-Heterocyclic Phosphenium Cation (NHP+) to Systematically Explore the Bonding of NHP+ Ligands with Nickel." Inorg. Chem. 54. (2015): 8717-8726; DOI: 10.1021/acs.organomet.5b00182.
Davidson, J. J.; DeMott, J. C.; Douvris, C.; Fafard, C. M.; Bhuvanesh, N.; Chen, C.-H.;Herbert, D. E.; Lee, C.I.; McCulloch, B. J.; Foxman, B. M.; Ozerov, O. V.. "Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Toward the Metal." Inorg. Chem. 54. (2015): 2916–2935 ; DOI: 10.1021/ic503062w.
Krogman, J. K.; Foxman, B. M.; Thomas, C. M.. "Formation and Subsequent Reactivity of Heterobimetallic Zr/Co µ-oxo and Cobalt Hydride Complexes." Organometallics 34. (2015): 3159–3166); DOI: 10.1021/acs.organomet.5b00182.
Lee, K. H.; Napoline, J. W.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Probing substituent effects in phosphinoamine ligands using Mo(CO)5L Complexes." Polyhedron 87. (2015): 354-360.
Posner, S. R.; Lorson, L. C.; Gell, A. R.; Foxman, B. M.. "Experimental Establishment of Mother-Daughter Orientation Relationships and Twinning Effects in Phase Transitions : A Great Legacy from Jack Gougoutas and Peggy Etter." Cryst. Growth Des. 15. (2015): 3407–3416; DOI: 10.1021/acs.cgd.5b00487.
Press, L. P.; McCulloch, B. J.; Gu, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Triflyloxy-substituted carboranes as useful weakly coordinating anions." Chem. Commun. 51. (2015): 14034-14037 DOI: 10.1039/C5CC05047B.
Wu, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "A heterobimetallic complex featuring a Ti–Co multiple bond and its application to the reductive coupling of ketones to alkenes." Chem. Sci. 6. (2015): 2044-2049; DOI: 10.1039/C4SC03772C.
Wu, B.; Gramigna, K. M.; Bezpalko, M. W.; Foxman, B. M.; Thomas , C. M.. "Heterobimetallic Ti/Co Complexes That Promote Catalytic N–N Bond Cleavage." Inorg. Chem. 54. (2015): 10909–10917; DOI: 10.1021/acs.inorgchem.5b01962.
Davidson, J. J.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Palladium Complexes of a New Phosphine-Amido-Siloxide Pincer Ligand With Variable Degrees of Protonation." Inorg. Chim. Acta 422. (2014): 70-77.
Falvello, L. R.; Foxman, B. M.; Murillo, C. A.. "Fitting the Pieces of the Puzzle: The Delta Bond." Inorg. Chem. 53. (2014): 9441−9456; DOI : 10.1021/ic500119h.
Falvello, L. R.; Foxman, B. M., Murillo, C. A.; Murillo, D. Associate Editors to: Cotton, F. A.. My Life in Chemistry : More Fun Than Fun (*Professor Cotton was murdered in 2007. The contributors helped bring the final work to publication.*). Elsevier, 2014.
Knight, S. E.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Coordination of N-heterocyclic phosphine- and phosphenium-containing pincer ligands to copper(I): Evidence for reactive electrophilic metal–phosphenium intermediates." Inorg, Chim. Acta 422. (2014): 181-187.
Kuppuswamy, S.; Bezpalko, M. W.; Powers, T. M.; Wilding, M. J. T.; Brozek, C. K.; Foxman, B. M.; Thomas, C. M.. "A series of C3-symmetric heterobimetallic Cr–M (M = Fe, Co and Cu) complexes." Chem. Sci. 5. (2014): 1617-1626 DOI: 10.1039/C3SC52943F.
Kuppuswamy, S.; Cass, T. R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Synthesis and Investigation of the Metal-Metal Interactions in Heterobimetallic Cr/Rh and Cr/Ir Complexes." Inorg. Chim. Acta 424. (2014): 167-172.
Kuppuswamy, S.; Powers, T. M.; Johnson, B. M.; Brozek, C. K.; Krogman, J. P.; Bezpalko, M. W.; Berben, L. A.; Keith, J.. M.; Foxman, B. M.; Thomas, C. M.. "One-Electron Oxidation Chemistry and Subsequent Reactivity of Diiron Imido Complexes." Inorg. Chem. 53. (2014): 5429–5437 DOI: 10.1021/ic403039x.
Marquard, S. L.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Interaction and Activation of Carbon-Heteroatom π-Bonds with a Zr/Co Heterobimetallic Complex." Organometallics 33. (2014): 2071–2079 DOI: 10.1021/om500217a.
Palita, C. M.; Graham, D. J.; Chen, C. H.; Foxman, B. M.; Ozerov, O. V.. "Reduction of CO2 to Free CO by a Pd(I)-Pd(I) Dimer." Chem. Commun. 50. (2014): 12840-12842; DOI: 10.1039/C4CC02438A.
Wu, B.; Sánchez, R. H.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation." Inorg. Chem. 53. (2014): 10021-10023; DOI: 10.1021/ic501490e.
Zhou, W.; Saper, N. I.; Krogman, J. P; Foxman, B. M.; Thomas, C. M.. "Effect of ligand modification on the reactivity of phosphinoamide-bridged heterobimetallic Zr/Co complexes." Dalton Trans. 43. (2014): 1984-1989 DOI: 10.1039/C3DT52133H.
Bezpalko , M. W. ; Foxman , B. M.; Thomas, C. M.. "Noninnocent Behavior of Bidentate Amidophosphido [NP]2– Ligands upon Coordination to Copper." Inorg. Chem. 52. (2013): 12329–12331 DOI: 10.1021/ic402257z.
Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Synthesis, Structure, and Reactivity of an Anionic Zr–Oxo Relevant to CO2 Reduction by a Zr/Co Heterobimetallic Complex." Inorg. Chem. 52. (2013): 3022–3031; : DOI: 10.1021/ic302473j.
Kuppuswamy, S.; Powers, T. M.; Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Vanadium–iron complexes featuring metal–metal multiple bonds." Chem. Sci. 4. (2013): 3557-3565 DOI: 10.1039/C3SC51337H.
Marquard , S. L.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M.. "Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene." J. Am. Chem. Soc. 135. (2013): 6018–6021 DOI: 10.1021/ja4022683.
Mathialagan, R.; Kuppuswamy, S.; De Denko , A. T.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M.. "Metal–Metal Bonding in Low-Coordinate Dicobalt Complexes Supported by Phosphinoamide Ligands." Inorg. Chem. 52. (2013): 701–706.
Napoline, J. W.; Krogman, J. P.; Shi, R.; Kuppuswamy, S.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Activation of E–H and E–E (E = S, O) Bonds by Heterobimetallic Zr/Co Complexes: Evidence for Both One- and Two-Electron Processes." European Journal of Inorganic Chemistry 2013. (2013): 3874–3882 10.1002/ejic.201300122.
Napoline, J. W.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "N–H activation of hydrazines by a heterobimetallic Zr–Co complex: promotion of one-electron chemistry at Zr." Chem. Commun. 49. (2013): 4388-4390 , DOI: 10.1039/C2CC35594A.
Pan ,B.; Evers-McGregor , D. A.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M.. "Multimetallic Complexes Featuring a Bridging N-heterocyclic Phosphido/Phosphenium Ligand: Synthesis, Structure, and Theoretical Investigation." Inorg. Chem. 52. (2013): 9583–9589 DOI: 10.1021/ic4012873.
Pan, B.; Pierre, S.; Bezpalko, M. W.; Napoline, J. W.; Foxman, B. M.; Thomas, C. M.. "Isolation of N-Heterocyclic Alkyl Intermediates en Route to Transition Metal N-Heterocyclic Carbene Complexes: Insight into a C–H Activation Mechanism." Organometallics 32. (2013): 704–710.
Shortsleeves, K. C.; Turnbull, M. M.; Seith, C. B.; Tripodakis, E. N.; Xiao, F.; Landee, C. P.; Dawe, L. N.; Garrett, D.; de Delgado, G. D.; Foxman, B. M.. "Crystallographic and magnetic studies of the 2-pyridone/copper halide system." Polyhedron 64. (2013): 110-121.
Walensky, J. R.; Fafard, C. M.; Guo, C.; Brammell, C. M.; Foxman, B. M.; Hall, M. B.; Ozerov, O. V.. "Understanding Pd–Pd Bond Length Variation in (PNP)Pd–Pd(PNP) Dimers." Inorg. Chem. 52. (2013): 2317–2322.
Zhang, Y.; Zhou, N.; Akella, S.; Kuang, Y.; Kim, D.; Schwartz, A.; Bezpalko; M. W.; Foxman, B. M.; Fraden, S.; Epstein, I. R.; Xu, B.. "Active Cross-Linkers that Lead to Active Gels." Angew. Chem. Int. Ed. 52. (2013): 11494–11498 10.1002/anie.201304437.
Zhou, W.; Marquard, S. L.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Catalytic Hydrosilylation of Ketones Using a Co/Zr Heterobimetallic Complex: Evidence for an Unusual Mechanism Involving Ketyl Radicals." Organometallics 32. (2013): 1766–1772 DOI: 10.1021/om301194g.
Evers, D. A.; Bluestein, A. H.; Foxman, B. M.; Thomas, C. M. "Synthesis and Investigation of the Metal-Metal Interactions in Early/Late Heterobimetallic Complexes Linking Group 5 Imido Fragments to Co(I)." Dalton Trans. 41. (2012): 8111-8115 DOI: 10.1039/C2DT00034B,.
Kuppuswamy, S. Cooper, B. G.; Bezpalko, M. W.; Foxman, B. M.; Powers, T. M.; Thomas, C. M.. "Synthesis and Structural Characterization of High Spin M/Cu (M = Mn, Fe) Heterobimetallic and Fe/Cu2 Trimetallic Phosphinoamides." Inorg. Chem. 51. (2012): 1866–1873.
Kuppuswamy, S.; Bezpalko, M. W.; Powers, T. M.; Turnbull, M. M.; Foxman, B. M.; Thomas, C. M.. "Utilization of Phosphinoamide Ligands in Homobimetallic Fe and Mn Complexes: The Effect of Disparate Coordination Environments on Metal–Metal Interactions and Magnetic and Redox Properties." Inorg. Chem. 51. (2012): 8225-8240.
Kuppuswamy, S.; Powers, T. M.; Johnson, B. M.; Bezpalko, M. W.; Brozek, C. K.; Foxman, B. M.; Berben, L. A.; Thomas, C. M.. "Metal–Metal Interactions in C3-Symmetric Diiron Imido Complexes Linked by Phosphinoamide Ligands." Inorg. Chem. ASAP, DOI: 10.1021/ic302108k. (2012).
Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Heterolytic addition of E–H bonds across Pt–P bonds in Pt N-heterocyclic phosphenium/phosphido complexes." Dalton Trans. 41. (2012): 9083-9090 DOI: 10.1039/C2DT30455D.
Pan, B.; Bezpalko, M.w.; Foxman, B. M.; Thomas, C.M.. "N-Heterocyclic Phosphenium Ligands as Sterically and Electronically-Tunable Isolobal Analogues of Nitrosyls." Inorg. Chem. 51. (2012): 4170–4179.
Bartelson, K. J.; Singh, R. P.; Foxman, B. M.; Deng , L.. "Catalytic asymmetric [4 + 2] additions with aliphatic nitroalkenes." Chem. Sci. 2. (2011): 1940-1944.
Brammell, C. M.; Pelton, E. J.; Chen, C.-H.; Yakovenko, A. A.; Weng, W.; Foxman, B. M.; Ozerov, O. V.. "Hafnium alkyl complexes of the anionic PNP pincer ligand and possible alkylidene formation." J. Organometal. Chem. 696. (2011): 4132-4137.
Day, G. S.; Pan, B.; Kellenberger, D. L.; Foxman, B. M.; Thomas, C. M.. "Guilty as charged: non-innocent behavior by a pincer ligand featuring a central cationic phosphenium donor." Chem. Commun. 47. (2011): 3634-3636.
DeMott, J. C.; Surawatanawong, P.; Barnett, S. M.; Chen, C.-H.; Foxman, B. M.; Ozerov , O. V.. "Experimental and computational exploration of the dynamic behavior of (PNP)BF2, a boron compound supported by an amido/bis(phosphine) pincer ligand." Dalton Trans. 40. (2011): 11562-11570.
Dhal, A. K.; Chatterjee, S.;Sandman, D. J.; Chen, C.-H.; Foxman, B. M.. "Co-crystals of Isonicotinamide and p-Cyanobenzoic Acid." J. Macromol. Sci., Chem. 48. (2011): 1038-1043.
Hickey, M. B.; Schlam, R. F.; Guo, C.; Cho, T. H.; Snider, B. B.; Foxman, B. M.. "Stereospecific solid-state cyclodimerization of bis(trans-2-butenoato)calcium and triaquabis(trans-2-butenoato)magnesium." CrystEngComm 13. (2011): 3146-3155.
Huacuja, R.; Graham, D. J.; Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Herbert, D. E.; Alliger, G.; Thomas, C. M.; Ozerov, O. V.. "Reactivity of a Pd(I)−Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium." J. Am.Chem. Soc. 133. (2011): 3280-3283.
Krogman, J. P.; Foxman, B. M.; Thomas, C. M.. "Activation of CO2 by a Heterobimetallic Zr/Co Complex." J. Am. Chem. Soc. 133. (2011): 14582–14585.
Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.. "Coordination of an N-Heterocyclic Phosphenium Containing Pincer Ligand to a Co(CO)2 Fragment Allows Oxidation To Form an Unusual N-Heterocyclic Phosphinito Species." Organometallics 30. (2011): 5560-5563.
Provencher, B. A.; Bartelson, K. J.; Liu, Y.; Foxman, B. M.; Deng, L.. "Structural Study-Guided Development of Versatile Phase-Transfer Catalysts for Asymmetric Conjugate Additions of Cyanide." Angew. Chem., Int. Ed. 50. (2011): 10565–10569.
Remenar, J. F.; Tawa, M. D.; Peterson, M. L.; Almarsson, Ö. Hickey, M. B.; Foxman, B. M.. "Celecoxib sodium salt: engineering crystal forms for performance." CrystEngComm 13. (2011): 1081-1089.
Setty, V. N.; Zhou, W.; Foxman,B. M.; Thomas, C. M.. "Subtle Differences Between Zr and Hf in Early/Late Heterobimetallic Complexes with Cobalt." Inorg. Chem. 50. (2011): 4647–4655.
Shang, W.; Hickey, M. B.; Enkelmann, V.; Snider, B. B.; Foxman, B. M.. "Chemo- and stereospecific solid-state dimerization of lithium trans-2-butenoate and lithium trans-2-butenoate formamide solvate." CrystEngComm 13. (2011): 4339-4350.
Zhu, Y.; Chen, C.-H.; Fafard, C.; Foxman, B. M.; Ozerov, O.V.. "Heterolytic Cleavage of B-H and B-B Bonds Across the N-Pd Bond in a Cationic (PNP)Pd Fragment." Inorg. Chem. 50. (2011): 7980-7987.
Alexander T. Radosevich, Jonathan G. Melnick, Sebastian A. Stoian, Deborha Bacciu, Chun-Hsing Chen, Bruce M. Foxman, Oleg V. Ozerov and Daniel G. Nocera. "Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3." Inorg. Chem. 48. (2010): 9214-9221.
Bacciu, D.; Chen, C. H.; Surawatanawong, P.; Foxman, B. M.; , Ozerov, O. V.. "High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand." Inorg. Chem. 49. (2010): 5328–5334 DOI: 10.1021/ic1004424.
Bennett P. Greenwood, Gerard T. Rowe, Chun-Hsing Chen, Bruce M. Foxman and Christine M. Thomas. "Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co." J. Am. Chem. Soc. 132. (2010): 44-45.
Cooper, B. G.; Fafard, C. M.; Foxman, B. M.; Thomas, C. M. "Electronic Factors Affecting Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes." Organometallics 29. (2010): 5179–5186 DOI: 10.1021/om100356a.
Douvris, C.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis." J. Am. Chem. Soc. (2010): 4946–4953 DOI: 10.1021/ja100605m.
Eugene Y. Cheung, Matthew L. Peterson, Renato Chiarella and Bruce M. Foxman. "A novel oxazolidinone antibiotic: RWJ-416457." Acta Cryst. C 66. (2010): o249–o251.
Jeffrey P. Wikstrom, Alexander S. Filatov, Elena A. Mikhalyova, Michael Shatruk, Bruce M. Foxman and Elena V. Rybak-Akimova. "Carbonate formation within a nickel dimer: synthesis of a coordinatively unsaturated bis(-hydroxo) dinickel complex and its reactivity toward carbon dioxide." Dalton Trans. 39. (2010): 2504-2514.
Lauren C. Gregor, Chung-Hsing Chen, Claudia M. Fafard, Lei Fan, Chengyun Guo, Bruce M. Foxman, Dmitry G. Gusev and Oleg V. Ozerov. "Heterolytic splitting of H–X bonds at a cationic (PNP)Pd center." Dalton Trans. 39. (2010): 3195-3202.
Singh, R. P.; Foxman, B. M.; Deng, L.. "Asymmetric Vinylogous Aldol Reaction of Silyloxy Furans with a Chiral Organic Salt." J. Am. Chem. Soc. 132. (2010): 9558–9560 DOI: 10.1021/ja103331t.
Thomas, C. M.; Napoline, J. W.; Rowe, G. T.; Foxman, B. M.. "Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes." Chem. Commun. (2010): 5790-5792 DOI: 10.1039/C0CC01272F.
A. F. DeBlase, D. C. Thong, J. M. Nadeau, D. Gebhart, J. Provo and B. M. Foxman. "syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.13,10.15,8.02,11.04,9]heptadecane deuterochloroform monosolvate." Acta Cryst. E65. (2009): o2427-o2428.
Foxman, B. M. ; Zanella, A.. "In Memoriam - Alan McLeod Sargeson (1930-2008)." Comments Inorg. Chem. 30. (2009): 4-6.
Foxman, Bruce M. "Transition metal complexes of 2-amino-3,5-dihalopyridines: Syntheses, structures and magnetic properties of (3,5-diCAPH)2CuX4 and (3,5-diBAPH)2CuX4." Dalton Trans. (2009): 10518-10526.
Greenwood, B. P.; Rowe, G.; Forman, S. I.; Chen, C.-H.; Foxman, B. M.; Thomas, C. M.. "Multielectron Redox Activity Facilitated by Metal-Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands." Inorg. Chem. 48. (2009): 6251-6260.
Kells, H.; Blumstein, A.; Sandman, D. J.; Chen, C.-H.; Foxman, B. M.. "Crystal and Molecular Structure of 1-Methyl-6-O-p-toluenesulfonyl-alpha-D-glucopyranoside dihydrate." J. Macromol. Sci., Part A 46. (2009): 1172-1179.
Li, L.; Landee, C. P.; Turnbull, M. M.; Foxman, B. M.. "Synthesis, structure determination, and magnetic properties of pentakis-[bis(hexafluoroacetylacetonato)1,2,4-triazinecopper(II)]." J. Coord. Chem. 62. (2009): 1207-1217.
Matthew T. Whited, Yanjun Zhu, Samuel D. Timpa, Chun-Hsing Chen, Bruce M. Foxman, Oleg V. Ozerov and Robert H. Grubbs. "Probing the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir." Organometallics 28. (2009): 4560-4570.
Bontemps, S.; Bouhadir, G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D.. "Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C3 Symmetry Supported by a Z-Type Ligand." Angew. Chem. Int. Ed. 47. (2008): 1481-1484.
Gatard, S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment." Organometallics 27. (2008): 6257-6263.
Giri, R.; Maugel, N.; Foxman, B. M.; Yu, J.-Q.. "Dehydrogenation of Inert Alkyl Groups via Remote C-H Activation: Converting a Propyl Group into a pi-Allylic Complex." Organometallics 27. (2008): 1667-1670.
Reddy, J.; Foxman, B. M.. "Crystal and Molecular Structure of a Second, High-Density Polymorph of Silver Malonate." J. Mol. Struct. 890. (2008): 227-231.
Sircoglou, M.; Bontemps, S.; Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D.. "Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine-Borane." J. Am. Chem. Soc. 130. (2008): 16729-16738.
Wang, X.; Sandman, D. J.; Enkelmann, V.; Chen, C.-H.; Foxman, B. M.. "Crystal and Molecular Structure of the bis-Ethyl urethane of 5,7-dodecadiyn-1,12,diol (ETCD)." J. Macromol. Sci., Part A 45. (2008): 915-917.
DeMott, J. C.; Basuli, F.; Kilgore, U. J.; Foxman, B. M.; Huffman, J. C.; Ozerov, O. V.; Daniel J. Mindiola, D. J.. "Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents." Inorg. Chem. 46. (2007): 6271-6276.
DeMott, J. C.; Guo, C.; Foxman, B. M.; Yandulov, D. V.; Ozerov, O. V.. "Five-coordinate aluminum complexes of a PNP ligand." Mendeleev Commun. 17. (2007): 63-65.
Fafard, C. M.; Adhikari, D.; Foxman, B. M.; Mindiola, D. J.; Ozerov, O. V.. "Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond." J. Am. Chem. Soc. 129. (2007): 10318-10319.
Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Covalent palladium-zinc bonds and their reactivity." Chem. Commun. (2007): 4465 - 4467.
Foley, J. B.; Gay, S. E.; Vela, M. J.; Foxman, B. M.; Bruce, A. E.; Bruce, M. R. M.. "Structure and Photochemical Isomerization of the Dinuclear Gold(I) Halide Bis(diphenylphosphanyl)ethylene Complexes: Correlation Between Quantum Yield and Aurophilicity." Eur. J. Inorg. Chem. 31. (2007): 4946-4951.
Foxman, B. M.; Ward, M. D.. "Molecules in the Solid State." MRS Bulletin 32. (2007): 534-539.
Gatard, S.; Guo, C.; Foxman, B. M.; Ozerov, O. V.. "Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions." Organometallics 26. (2007): 6066-6075.
Gerber, L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O. V.. "Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand." Organometallics 26. (2007): 4866-4868.
Gilbertson, J. D.; Szymczak, N. K.; Crossland, J. L.; Miller, W. K.; Lyon, D. K.; Foxman, B. M.; Davis, J.; Tyler, D. R.. "Coordination Chemistry of H2 and N2 in Aqueous Solution. Reactivity and Mechanistic Studies Using trans-FeII(P2)2X2-Type Complexes (P2 = a Chelating, Water-Solubilizing Phosphine)." Inorg. Chem 46. (2007): 1205-1214.
Ozerov, O. V.; Guo, C.; Foxman, B. M.. "Missing link: PCP pincer ligands containing P-N bonds and their Pd complexes." J. Organometal. Chem. 691. (2007): 4802-4806.
Tanke, R. S.; Foxman, B. M.. "2-Amino-4-methylbenzothiazole." Acta Crystallogr., Sect. E 63. (2007): 4718.
Wang, Y.; Li, H.; Wang, Y.-Q.; Liu, Y.; Foxman, B. M.; Deng, L.. "Asymmetric Diels-Alder Reaction of 2-Pyrones with Bifunctional Organic Catalysts." J. Am. Chem. Soc. 129. (2007): 6364-6365.
Weng, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.. "Palladium Complexes of a P2C= Ligand Containing a Central Carbene Moiety." Organometallics 26. (2007): 3315-3320.
Zhu, Y.; Fan, L.; Chen, C.; Finnell, S. R.; Foxman, B. M.; Ozerov, O. V.. "C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity." Organometallics 26. (2007): 6701-6703..
Zou, Y.; Chen, C.-H.; Taylor, C. D.; Foxman, B. M.; Snider, B. B.. "Formal Synthesis of (±)-Platensimycin." Org. Lett. 9. (2007): 1825-1828.
Sae-Lim, C.; Sandman, D. J.; Foxman, B. M.. "Synthesis and Crystallographic Study of 1,6-bis-(N-phenothiazinyl)-2,4-hexadiyne." J. Macromol. Sci., Part A 43. (2006): 1929-1936.
Yang, L; Foxman, B. M.. "Crystal and Molecular Structure of Ammonium trans-2-Butenoate, and a Preliminary Investigation of its Solid-State Reactivity." Mol. Cryst. Liq. Cryst. 456. (2006): 25-33.
Cannon, A. S.; Foxman, B. M.; Guarrera, D. J.; Warner, J. C.. "Noncovalent Derivatives of Hydroquinone: Complexes with Trigonal Planar Tris-(N,N-dialkyl)trimesamides." Cryst. Growth Des. (2005): 407-411.
Guo, C.; Hickey, M. B.; Guggenheim, E. R.; Enkelmann, V.; Foxman, B. M.. "Conformational Polymorphism of Methacrylamide (accepted for publication)." Chem. Commun (2005): 2220-2222.
Hickey, M. B.; Foxman, B. M.. "Crystal and Molecular Structure of Crotonohydroxamic Acid, and a Preliminary Investigation of the Solid-State Reactivity of the Acid and Its Salts." Mol. Cryst. Liq. Cryst. 440. (2005): 195-205.
Li, H.; Wang, Y.; Tang, L.; Wu, F.; Liu, X.; Guo, C.; Foxman, B. M.; Deng, L. Angew. "Stereocontrolled Creation of Adjacent Quaternary and Tertiary Stereocenters via a Catalytic, Diastereoselective and Enantioselective Conjugate Addition." Angew. Chem. Int. Ed 44. (2005): 105-108.
Njus, J. M.; Sandman, D. J.; Yang, L.; Foxman, B. M.. "Thermal Solid-State Polymerization of p-Ethynylbenzoic Acid." Macromolecules 38. (2005): 7645-7652.
R.; Watson, L. A.; Guo, C.; Foxman, B. M.; Ozerov, O. V.. "Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center." Organometallics 24. (2005): 186-189.
Weng, W.; Guo, C.; Moura, C.; Yang, L.; Foxman, B. M.; Ozerov, O. V.. "Competitive Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and Iridium." Organometallics 24. (2005): 3487-3499.
Cooper, R. I.; Foxman, B. M.; Yang, L.. "CIF Applications. CIF2CRY: for Input of Structural CIF Data into the CRYSTALS program." J. Appl. Cryst. 37. (2004): 669-671.
Fan, L.; Yang, L.; Guo, C.; Foxman, B. M.; Ozerov, O. V.. "N-C cleavage in pincer PNP complexes of palladium." Organometallics 23. (2004): 4778-4787.
Foxman,B M, Fan, L.; Ozerov, O. V.. "N H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand." 23. (2004): 326-328.
Foxman,Bruce M with Fan, L.; Yang, L.: Guo C.: Foxman B. M.: Ozerov, O. V Organometallics. N-C cleavage pincer PNP complesex of palladium. 2004.
Foxman,Bruce M with Ozerov, O.V.: Guo, C.: Fan. L.: Foxman, B.M.. "Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nicke, Palladium and Platinum. Organometallics, 2004.
Foxman,Bruce M with Weng, W,; Yang, L.; Foxman B.M.: Ozerov, O. V. Organometallic,. Chelate-Enforced Phosphine Coordination Enabbles a-Abstraction to Give Zirconium Alkylidenes. 2004.
Foxman,Bruce M witn Zhan, Z.: Uth, S; Sandman, D. J.: Foxman, B.M.J Phys. Org.. "Structure, polymorphis and thermal properties or phenyliminoisoindolines". Chem. 2004, 2004.
Ozerov, O. V.; Guo, C.; Fan. L.; Foxman, B. M.. "Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nickel, Palladium, and Platinum." Organometallics 23. (2004): 5573-5580.
Ozerov, O. V.; Guo, C.; Papkov, V. A.: Foxman, B.M.. "Facile Oxidative Addition of N-C and NH Bonds to Monovalent Rhodium and Iridium." J. Am. Chem. Soc. 126. (2004): 4792-4793.
Ozerov,O. V.; Guo, C.; Papkov, V. A.; Foxman, B. M.. "Facile Oxidative Addition of N-C and NH Bonds to Monovalent Rhodium and Iridium." J. Am. Chem. Soc. 126. (2004): 4792-4793.
Weng, W.; Yang, L.; Foxman, B. M.; Ozerov, O. V.. "Chelate-Enforced Phosphine Coordination Enables a-Abstraction to Give Zirconium Alkylidenes." Organometallics 23. (2004): 4700-4705.
Zhang, Z.-Q.; Njus, J. M.; Sandman, D. J.; Guo, C.; Foxman, B. M; Erk, P.; van Gelder, R.. "Diiminoisoindoline: tautomerism, conformations, and polymorphism." Chem. Commun. (2004): 886-887.
Zhang, Z.; Uth, S; Sandman, D. J.; Foxman, B. M.. "Structure, polymorphism, and thermal properties of phenyliminoisoindolines." J. Phys. Org. Chem 17. (2004): 769-776.