Grace Han

Landsman Career Development Chair of Science

gracehan@brandeis.edu
781-736-2576
Edison-Lecks Science Building, 307

Departments/Programs

Chemistry

Degrees

Massachusetts Institute of Technology, Ph.D.

Expertise

Organic materials chemistry; photo-switching chemistry; solar energy conversion and storage

Profile

Research in our group focuses on developing a wide range of versatile and unique optically controlled molecular switches for energy conversion/storage and optoelectronic applications. Photo-switchable molecular systems absorb light and rapidly respond via structural change that provides control over a broad array of properties in diverse organic and soft materials systems. These reversible switches allow for the repeatable operation of energy harvesting schemes on a large scale as well as the discrete on/off modulation of nanoscale biological systems via their structural changes at the molecular level.

Courses Taught

CHEM	91g	Introduction to Research Practice
CHEM	121a	Inorganic Chemistry I, Lectures
CHEM	161a	Polymer and Inorganic Materials Chemistry
CHEM	300c	Chemistry Colloquium

Awards and Honors

AFOSR YIP Award (2021)

NSF CAREER Award (2021)

Provost Research Award (2021)

The Landsman Career Development Chair in the Sciences (2020)

Scholarship

G. G. D. Han and Y. Shi. Direct Sunlight-Activated Phase Change Materials for Controlled Heat Storage and Triggered Release. Patent US Provisional 63/144,737.

G. G. D. Han, M. J. Fuchter, J. C. Grossman, M. A. Gerkman, and R. Gibson. Arylazopyrazoles and Their Use for Long-Term Thermal Energy Storage. Patent PCT/US2021/016381.

Q. Qiu, Y. Shi, and G. G. D. Han*. "Solar Energy Conversion and Storage by Photoswitchable Organic Materials in Diverse Phases." (2021).

Y. Shi, M. A. Gerkman, Q. Qiu, S. Zhang, and G. G. D. Han*. "Sunlight-Activated Phase Change Materials for Controlled Heat Storage and Triggered Release." Journal of Materials Chemistry A (2021).

A. Gonzalez, E. S. Kengmana, M. V. Fonseca, and G. G. D. Han*. "Solid-State Photoswitching Molecules: Structural Design for Isomerization in Condensed Phase." Materials Today Advances 6. (2020): 100058.

C.-C. A. Voll, G. Markopoulos, T. C. Wu, M. Welborn, J. U. Engelhart, S. Rochat, G. G. D. Han, G. T. Sazama, T.-A. Lin, T. Van Voorhis, M. A. Baldo, and T. M. Swager. "Lock-and-Key Exciplexes for Thermally Activated Delayed Fluorescence." Organic Materials 2. (2020): 1-10.

E. S. Kengmana, J. K. Lee, X. Li, J. H. Warner, and G. G. D. Han*. "Self-Assembly of Bowlic Supramolecules on Graphene Imaged at the Individual Molecular Level using Heavy Atom Tagging." Small 16. (2020): 2002860.

G. G. D. Han, M. J. Fuchter, J. C. Grossman, M. A. Gerkman, and R. Gibson. Arylazopyrazoles and Their Use for Long-Term Thermal Energy Storage. Patent 62/969,634.

M. A. Gerkman and G. G. D. Han*. "Toward Controlled Thermal Energy Storage and Release in Organic Phase Change Materials." Joule (Cell Press) 4. (2020): 1621-1625.

M. A. Gerkman, J. K. Lee, X. Li, Q. Zhang, M. Windley, M. V. Fonseca, Y. Lu, J. H. Warner, and G. G. D. Han*. "Direct Imaging of Individual Molecular Binding to Clean Nanopore Edges in 2D Monolayer MoS2." ACS Nano 1. (2020): 3-6.

M. A. Gerkman, R. Gibson, J. Calbo, Y. Shi, M. J. Fuchter*, G. G. D. Han*. "Arylazopyrazoles for Long-Term Thermal Energy Storage and Optically-Triggered Heat Release below 0 °C." Journal of the American Chemical Society 142. (2020): 8688-8695.

X. Li, J. K. Lee, Y. Lu, M. A. Gerkman, E. S. Kengmana, M. V. Fonseca, J. H. Warner, and G. G. D. Han*. "Precursor Design for High Density Single Pt Atom Sites on MoS2: Enhanced Stability at Elevated Temperatures and Reduced 3D Clustering." Chemistry of Materials 32. (2020): 2541-2551.

G. G. D. Han, M. Gerkman, and Y. Shi. Thermal Storage Materials and Applications Thereof. Patent 62/843,136.

G. G. D. Han. Light-Responsive Temporary Adhesives. Patent 62/843,136.

J. K. Lee, I. Bulut, M. Rickhaus, T. Chen, X. Li, G. G. D. Han, G. A. D. Briggs, H. L. Anderson, J. H. Warner. "Metal Atom Markers for Imaging Epitaxial Molecular Self-Assembly on Graphene by Scanning Transmission Electron Microscopy." ACS Nano 13. (2019): 7252-7260.

M. A. Gerkman, S. Sinha, J. H. Warner, and G. G. D. Han*. "Direct Imaging of Photoswitching Molecular Conformations Using Individual Metal Atom Markers." ACS Nano 13. 1 (2019): 87-96.

M. A. Gerkman, S. Yuan, P. Duan, J. Taufan, K. Schmidt-Rohr, and G. G. D. Han*. "Phase Transition Dynamics of Spiropyran Molecular Switches." Chemical Communications 55. (2019): 5813-5816.

S. Fang, Y. Wen, C. S. Allen, C. Ophus, G. G. D. Han, A. I. Kirkland, E. Kaxiras, and J. H. Warner. "Atomic Electrostatic Maps of 1D Channels in 2D Semiconductors using 4D Scanning Transmission Electron Microscopy." Nat. Commun. 10. (2019): 1127.

G. G. D. Han, B. Smith, W. Xu, J. H. Warner, and J. C. Grossman. "Nanoporous Silicon-Assisted Patterning of Monolayer MoS2 with Thermally Controlled Porosity: A Scalable Method for Diverse Applications." ACS Appl. Nano Mater. 1. 7 (2018): 3548–3556.

G. G. D. Han, J. H. Deru, E. N. Cho, and J. C. Grossman. "Optically Regulated Thermal Energy Storage in Diverse Organic Phase-Change Materials." Chem. Commun. 54. (2018): 10722–10725.

E. N. Cho, D. Zhitomirsky, G. G. D. Han, Y. Liu, and J. C. Grossman. "Molecularly Engineered Azobenzene Derivatives for High Energy Density Solid-State Solar Thermal Fuels." ACS Appl. Mater. Interfaces 9. 10 (2017): 8679–8687.

G. G. D. Han, H. Li, and J. C. Grossman. "Optically-Controlled Long-Term Storage and Release of Thermal Energy in Phase-Change Materials." Nat. Commun. 8. (2017): 1446.

G. G. D. Han, K.-H. Tu, F. Niroui, W. Xu, S. Zhou, X. Wang, V. Bulović, C. A. Ross, J. H. Warner, and J. C. Grossman. "Photoluminescent Arrays of Nano-Patterned Monolayer MoS2." Adv. Funct. Mater. 27. (2017): 1703688.

H. Li, S. Wang, H. Sawada, G. G. D. Han, T. Samuels, C. S. Allen, A. I. Kirkland, J. C. Grossman, and J. H. Warner. "Atomic Structure and Dynamics of Single Pt Atom Interactions with Monolayer MoS2." ACS Nano 11. 3 (2017): 3392-3403.

S. Wang, H. Sawada, Q. Chen, G. G. D. Han, C. S. Allen, A. I. Kirkland, and J. H. Warner. "In Situ Atomic-Scale Studies of the Formation of Epitaxial Pt Nanocrystals on Monolayer Molybdenum Disulfide." ACS Nano 11. 9 (2017): 9057-9067.

G. D. Han, A. Maurano, J. G. Weis, V. Bulović, and T. M. Swager. "VOC Enhancement in Polymer Solar Cells with Isobenzofulvene–C60 Adducts." Org. Electron. 31. (2016): 48-55.

G. D. Han, S. S. Park, Y. Liu, D. Zhitomirsky, E. Cho, M. Dincă, and J. C. Grossman. "Photon Energy Storage Materials with High Energy Densities Based on Diacetylene–Azobenzene Derivatives." J. Mater. Chem. A 4. (2016): 16157-16165.

S. Chang, G. D. Han, J. G. Weis, H. Park, O. Hentz, Z. Zhao, T. M. Swager, and S. Gradečak. "Transition Metal-Oxide Free Perovskite Solar Cells Enabled by a New Organic Charge Transport Layer." ACS Appl. Mater. Interfaces 8. 13 (2016): 8511–8519.